Journal
TETRAHEDRON LETTERS
Volume 57, Issue 11, Pages 1220-1223Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.02.001
Keywords
Aldol reaction; Thiourea; Bifunctional catalyst; Organocatalysis; Trifluoromethyl ketones
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An enantioselective aldol reaction of aryl methyl ketones with aryl trifluoromethyl ketones catalyzed by tertiary amino thiourea has been established. Under mild conditions, the corresponding beta-trifluoromethyl-beta-hydroxy ketone products were obtained with up to 89% ee. (C) 2016 Elsevier Ltd. All rights reserved.
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