Journal
TETRAHEDRON LETTERS
Volume 57, Issue 10, Pages 1150-1153Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.01.107
Keywords
Aza-Michael-type addition; Supported ionic liquid; Magnetic support; Diatomaceous earth; Heteropoly acid
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Funding
- Research Affairs Division at Amirkabir University of Technology (AUT), Tehran
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In this work, we have obtained substituted amines under mild conditions in good yields using the Aza-Michael-type addition of various amines to vinyl compounds catalysed by a supported ionic liquid incorporating an anionic heteropoly acid. Different catalysts, including Lewis acids, Bronsted acids and heteropoly acids were investigated in which heteropoly acids having dual Bronsted and Lewis acid characteristics were excellent catalysts. The ionic liquid incorporating a polytungstate anion supported on magnetic diatomaceous earth as a magnetically separable heterogeneous catalyst offered the best results in terms of yield. The solid nanocatalyst was easily removed with a magnet. (C) 2016 Elsevier Ltd. All rights reserved.
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