Journal
TETRAHEDRON LETTERS
Volume 57, Issue 7, Pages 800-803Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.01.029
Keywords
Indoles; Nitroolefins; Acylation reaction; Ketone
Categories
Funding
- Natural Science Foundation of China [81403268, 21102003]
- Scientific Research Foundation for the Introduction of Talent and Young Teachers
- Scientific Research Foundation of Anhui University of Science Technology [QN201508]
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A novel and efficient cerium(III)-catalyzed C-3-selective acylation of N -H indoles using nitroolefins as acylating reagents was first developed. It was found that the use of CeCl3 as a catalyst achieves an unexpected and highly efficient C-C bond cleavage. (C) 2016 Elsevier Ltd. All rights reserved.
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