4.4 Article

Triacetic acid lactone as a common intermediate for the synthesis of 4-hydroxy-2-pyridones and 4-amino-2-pyrones

Journal

TETRAHEDRON LETTERS
Volume 57, Issue 11, Pages 1293-1295

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.02.043

Keywords

2-Pyrone; Triacetic acid lactone; Amine; 4-Amino-2-pyrones; 4-Hydroxy-2-pyridones

Funding

  1. NSF Engineering Center for Biorenewable Chemicals (CBiRC) NSF [EEC-0813570]

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At ambient temperature, triacetic acid lactone reacts with amines to produce 4-amino-2-pyrones. If the temperature is raised to 100 degrees C, 4-hydroxy-2-pyridones are generated. (C) 2016 Elsevier Ltd. All rights reserved.

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