Journal
TETRAHEDRON
Volume 72, Issue 35, Pages 5521-5529Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.07.043
Keywords
Sodium amalgam; beta-Ketosulfones; Desulfonylation; Alcohols
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Funding
- Ministry of Science and Technology of the Republic of China [MOST 105-2113-M-037-001]
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Sodium amalgam mediated desulfonylative reduction of beta-ketosulfones in MeOH at rt affords alcohols in good yields via radical desulfonylation of O-ketosulfones and sequential Bouveault-Blanc reduction of the resulting ketones. (C) 2016 Elsevier Ltd. All rights reserved.
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