Journal
TETRAHEDRON
Volume 72, Issue 49, Pages 8000-8003Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.10.029
Keywords
Dioxygenation; Hydroxamic acid; Radical addition; Selective oxidation; 1-Phenylethanol
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Funding
- National Science Foundation of China NSF [21402066]
- Natural Science Foundation of Jiangsu Province [BK20140139]
- Fundamental Research Funds for the Central Universities [JUSRP11419]
- MOE&SAFEA for the 111 project [B13025]
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A highly selective radical dioxygenation of alkenes using hydroxamic acid and O-2 with 5-10 mol % of tert-butyl hydroperoxide as a catalyst was developed. On the basis of this newly developed strategy, a wide range of phenylethanol derivatives with a variety of functional groups can be effectively synthesized. (C) 2016 Elsevier Ltd. All rights reserved.
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