Journal
TETRAHEDRON
Volume 72, Issue 42, Pages 6611-6615Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.08.073
Keywords
Ring-rearrangement metathesis; Spirocycles; Oxacycles; Norbornene derivatives
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Funding
- Department of Science and Technology (DST)-India
- DST
- University Grants Commission (UGC) India
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Norbornene derivatives containing oxygen atom(s) are found to undergo ring-rearrangement metathesis sequence to deliver cyclic ethers. Here, we have established a simple, efficient and an atom-economic process for the synthesis of fused and spiro-oxacyclic compounds starting with cyclopentadiene. Compounds prepared in this study are difficult to assemble by conventional retrosynthetic routes. (C) 2016 Published by Elsevier Ltd.
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