Journal
TETRAHEDRON
Volume 72, Issue 18, Pages 2227-2232Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.03.006
Keywords
Macrocycle; Tetrapyrazole; Liquid-liquid extraction; Litium; Spectroscopy
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The synthesis of a new functionalized tetrapyrazolic macrocycle with two bidentate bipyrazolic subunits and a lipophilic moiety bearing a donor-group is described. The complexing properties of this macrocycle towards the alkali metal ions (Li+, Na+, K+, Cs+) were studied by liquid liquid extraction, and they showed a good extraction ability for Li+ and Na+, and a remarkable selectivity for the lithium cation in competitive conditions. (C) 2016 Elsevier Ltd. All rights reserved.
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