Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 6, Pages 804-815Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561321
Keywords
palladium; directing groups; olefination; ortho; meta-C-H bond; removable auxiliary
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Funding
- SERB, India [EMR/2015/000164]
- UGC-India
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Site selective C-H bond activation/C-C bond formation is an ideal target for organic chemists owing to the ubiquitous nature of C-H bonds in natural products. A particular aryl C-H bond can be predictably activated by a directing group. However, the majority of strong and weak coordinating directing groups have been implemented for ortho-C-H bond activation/C-alkenylation. More recently, meta-C-H functionalization has been promoted by fine-tuning directing templates. In this short review, we have summarized recent progress in palladium-catalyzed directing group/template-assisted ortho/meta-C-H olefination.
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