Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 10, Pages 1483-1490Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561567
Keywords
palladium; Heck reaction; alkylboronate; diastereoselective; chroman; benzopyran
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Toronto
- Alphora Research Inc.
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A diastereoselective palladium-catalyzed domino Heck/arylborylation of aryl iodides yielding an alkylboronate containing a chroman is reported. The generated alkylpalladium(II) intermediate is intercepted with bis(pinacolato)diboron (B(2)pin(2)) in good yield as a single diastereomer.
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