Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 21, Pages 3696-3700Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1562783
Keywords
dihydroxylation; diols; acrylates; alkenes; potassium permanganate; quaternary ammonium salts
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Funding
- Jiangsu University [13JD062]
- National Natural Science Foundation of China [21402067]
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An efficient and economic procedure was developed for the dihydroxylation of various olefin derivatives with commercial KMnO4 as the oxidant in the presence of a quaternary ammonium salt. This practical procedure is suitable for large-scale production of cis-dihydroxy compounds, even those bearing primary and secondary alcohol groups, without overoxidation.
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