Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 9, Pages 1399-1406Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561366
Keywords
microwave irradiation; phenols; chromenes; protecting groups; Claisen rearrangement
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Funding
- Equal Opportunities Fund of the Faculty of Science, Universitat Potsdam
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para-Substituted aryl prenyl ethers undergo a deprenylation reaction upon microwave irradiation. This offers the opportunity to use a prenyl ether as a thermolabile protecting group in the synthesis of natural products with a chromone structure, which proceeds via a tandem deprenylation/6-endo-cyclization sequence.
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