Journal
SYNLETT
Volume 27, Issue 20, Pages 2795-2798Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588595
Keywords
Betti bases; benzothiazoles; phenols; aldehydes; quinone methides
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Funding
- SERB-India [SB/FT/LS-297/2012]
- UGC-India [41/224/2012 (SR)]
- CSIR, India
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A three-component one-pot method has been developed for the synthesis of 2-[( benzo[d]thiazol-2-ylamino)(phenyl) methyl] phenols from a variety of aldehydes, 2-amino-1,3-benzothiazoles, and phenols. Phenol, substituted phenols, and polyhydroxybenzenes participated well, providing the corresponding derivatives in good yields. In the case of polyhydroxybenzenes, for which the formation of positional isomers or dimers might have been possible, the sterically less hindered positional isomer was formed exclusively via the ortho-quinone methide.
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