Journal
SYNLETT
Volume 27, Issue 9, Pages 1303-1309Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561385
Keywords
indoline; indolenine; indoxyl; aza-pinacol rearrangement; aza-semipinacol rearrangement
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Funding
- Tsinghua University
- 1000 Talents Recruitment Program
- Collaborative Innovation Center for Biotherapy
- National Science Foundation of China [21302107]
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Although the widespread usage of aza-pinacol and aza-semipinacol rearrangements as synthetic methods has not been found, these synthetic transformations offer novel tactics for the preparation of nitrogen-containing heterocycles and natural alkaloids. Herein, we briefly discuss the most recent developments in this area and present our strategy based on aza-pinacol rearrangements for the synthesis of indolines and indolenines. 1 Introduction 2 Recently Developed Aza-Pinacol and Aza-Semipinacol Rearrangements 3 Indoline/Indolenine Synthesis Employing Aza-Pinacol Rearrangements as the Key Strategy 4 Conclusion
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