Journal
SYNLETT
Volume 27, Issue 10, Pages 1450-1455Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561416
Keywords
transition metal; Masse shot; bromination; ruthenium; meta-selective
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Funding
- National Basic Research Program of China [2015CB856500]
- National Natural Science Foundation of China [21302136]
- Tianjin Natural Science Foundation [13JCQNJC04800]
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Reviewed herein are a number of modern approaches for the meta-selective direct C-H functionalization of substituted arenes, including a recent discovery on Ru-catalyzed meta-bromination is also discussed with the mechanistically interesting features (ortho-metallation and para-functionalization relay). 1 Introduction 2 Transition-Metal-Mediated meta-C-H Activation 3 Ruthenium-Catalyzed meta-C-H Bromination 4 Conclusion and Future Directions
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