4.7 Article

Hydroxyapatite based and anodic Titania nanotube biocomposite coatings: Fabrication, characterization and electrochemical behavior

Journal

SURFACE & COATINGS TECHNOLOGY
Volume 287, Issue -, Pages 67-75

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2015.12.062

Keywords

Titanium alloy; Anodizing; Hydroxyapatite; Electrochemical deposition; Nano-biocomposite; TiO2 nanotubes

Funding

  1. Iran Nanotechnology Initiative Council
  2. Research Council of the Sharif University of Technology

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The main challenges of biological implants are suitable strength, adhesion, biocompatibility and corrosion resistance. This paper discusses fabrication, characterization and electrochemical investigation of anodized Ti6Al4V without and with a hydroxyapatite (HA) layer, HA/TiO2 nanoparticles (NPs) and HA/TiO2 nanotubes (HA/anodized). X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS) were used to characterize and compare properties of different samples. Dense HA with uniform distribution and 12.8 +/- 2 MPa adhesive strength enhanced to 19.2 +/- 4 MPa by the addition of TiO2 nano particles and enhanced to 23.1 +/- 4 MPa by the deposition of a TNT interlayer was fabricated by an anodic oxidation process. EIS analysis divulged the polarization behavior of various layers formed, on a Ti6Al4V substrate. Electrochemical measurements indicated polarization passivation due to incorporation of TiO2 nanoparticles to HA. Hydroxyapatite on a TNT layer revealed lower corrosion resistance than a HA/TiO2 nanoparticle sample due to the vacuolar nature of TNT conformation. The passivation current density of the Ti6Al4V alloy coated with a HA/TiO2 nanocomposite (0.125 mu A/cm(2)) was less than 1% of the bare substrate. (C) 2015 Elsevier B.V. All rights reserved.

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