4.7 Article

Tungsten doped indium oxide film: Ready for bifacial copper metallization of silicon heterojunction solar cell

Journal

SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 144, Issue -, Pages 359-363

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.solmat.2015.09.033

Keywords

IWO film; Copper metallization; Heterojunction; Long term stability

Funding

  1. National High-tech R&D Program of China (863 Program) [2011AA050501]
  2. Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences [KGCX2-YW-399+11]
  3. MacDermid

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Tungsten doped indium oxide (IWO) film was deposited by reactive plasma deposition technology for a-Si:H/c-Si heterojunction (SHJ) solar cell. The average transmittance and absorption of IWO film from 350 to 1200-nm wavelength was 88.33% and 2.16% respectively. The hall mobility is 77.8 cm(2)/Vs, with a corresponding carrier concentration of 2.86E20 cm-3 and resistivity of 2.80E-04 Omega cm. Based on high-performance IWO film, the 5 in. SHJ solar cell with efficiency value of 22.03% and power of 3.37W was obtained by electroplated copper metallization technology. Compared with screen printed SHJ solar cells, the fingers of electroplated cells show finer width, higher aspect ratio and lower series resistance, resulting in increased fill factor and higher efficiency. The long term stability test of copper electroplated cells reveal that IWO film has excellent stability at the solar cell modules' operating temperature and can prevent copper diffusion effectively, which makes copper metallization of high efficiency heterojunction solar cell possible. (C) 2015 Elsevier B.V. All rights reserved.

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