Synergistic enhancement of thermal conductivity for expanded graphite and carbon fiber in paraffin/EVA form-stable phase change materials

Thermally conductive form-stable phase change materials (FSPCMs) were prepared by using ethylene-vinyl acetate (EVA), paraffin, expanded graphite (EG) and carbon fiber (CF) as row materials. Two-dimensional EG and one-dimensional CF were used as thermally conductive fillers. Paraffin and EVA were phase change material (PCM) and supporting material, respectively. Differential scanning calorimetry (DSC) and leakage rate testing results indicated that FSPCMs owned the melting temperature of 45.63 degrees C and the latent heat of 167.4 J/g. The prepared material had a small leakage rate which was less than 2%. Scanning electron microscope (SEM) results shown that EG and CF possessed excellent compatibility in FSPCMs. In-situ X-ray diffraction (XRD) tests demonstrated that the crystal behaviors of paraffin and EVA were changed with the phase transformation. Thermal conductivity results shown that thermal conductivity of FSPCMs in horizontal orientation was higher than that in longitudinal orientation. EG and CF have synergistic enhancement to thermal conductivity of FSPCMs. (C) 2016 Elsevier Ltd. All rights reserved.