Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 222, Issue -, Pages 1184-1192Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2015.08.008
Keywords
HSO4-; Schiff base; Colorimetric; Fluorescent; BODIPY; Hydrolysis
Funding
- National Natural Science Foundation of China [21274045]
- Pearl River in Guangzhou city of Nova of Science and Technology Special Funded Projects [2012J2200009]
- Fundamental Research Funds for the Central Universities [2015ZZ037]
- Natural Science Foundation of Guangdong Province [10351064101000000]
- National Basic Research Program of China [2012CB720801]
Ask authors/readers for more resources
A novel colorimetric fluorescent chemosensor for HSO4- using BODIPY-based Schiff base (L) has been developed. L is capable of showing high selectivity and sensitivity toward HSO4- over a wide range of other interfering anions. In presence of HSO4-, L shows a significant blue-shift in the absorption spectra from 523 to 497 nm and an increase of the ratio of the absorbance at 497 and 523 nm (A(497)/A(523)) over 150-fold, which induces color changes from pink to yellow. Non-fluorescent L upon interaction with HSO4- ions displays a 114-fold fluorescence enhancement at 533 nm, resulting in strong green emission. The binding mode of L with HSO4- has been investigated by Job's plot, H-1 NMR and HRMS measurements. The sensing mechanism is suggested to proceed via a hydrolysis process. In addition, the cell imaging experiments demonstrate that L can be successfully applied as a bioimaging agent for monitoring HSO4- in HeLa cells. (C) 2015 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available