4.7 Article

Buckling failure in air-plasma sprayed thermal barrier coatings induced by molten silicate attack

Journal

SCRIPTA MATERIALIA
Volume 113, Issue -, Pages 71-74

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2015.09.029

Keywords

Thermal barrier coatings; Air-plasma spray; Buckling; Liquid infiltration; Calcium-magnesium-alumino-silicate

Funding

  1. 1000 Plan Program
  2. Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning [SHDP201303]
  3. National Natural Science Foundation of China [51271120]
  4. Key Program for Basic Research of Shanghai Science and Technology Committee [12DJ1400400]

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buckling phenomenon in air-plasma sprayed yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) induced by calcium-magnesium-alumino-silicate (CMAS) attack was investigated. The liquid CMAS infiltration due to capillary force weakened the interface and introduced a significant volume expansion (32%) in the top coat, leading to a large scale buckling of the TBC at high temperature. The dissolution and tetragonalmononiclic phase transformation of YSZ induced by CMAS only has a negligible contribution. (C) 2015 Elsevier Ltd. All rights reserved.

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