Journal
SCIENCE OF THE TOTAL ENVIRONMENT
Volume 550, Issue -, Pages 241-247Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.scitotenv.2016.01.015
Keywords
Biochar; Biocarbon; Functionalization; Biomass; Pyrolysis
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Funding
- Ontario Ministry of Agriculture, Food and Rural Affairs (OMAFRA)-University of Guelph Product Development and Enhancement through Value Chains Research Theme [200399]
- OMAFRA-University of Guelph Bioeconomy for Industrial Uses Research Theme [030055]
- Natural Sciences and Engineering Research Council of Canada (NSERC), Canada [400322]
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Oxidative acid treatments of biochar produced from Miscanthus were performed in this study using nitric acid, sulfuric acid, and a mixture of both. The structural and morphological changes of the add-treated biochar were investigated using Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Raman spectroscopy, organic elemental analysis and energy-dispersive X-ray spectroscopy (EDS). Improved surface functionality of the treated biochars was observed in their respective FT-lR spectra through the presence of nitro and carboxylic acid functional groups. SEM-EDS and elemental analysis revealed a large increase in the oxygen to carbon ratio in the biochar, which was evidence of chemical oxidation from the acid treatment. Further, TGA study showed the reduced thermal stability of acid-treated biochar over 200 degrees C due to the increased oxygen content. Acid treatments also influenced the graphitic structure of the biochar, as observed in the Raman spectra. The results suggest that biochar can be successfully functionalized for composite applications and provide a sustainable alternative to petroleum-based carbon additives. (C) 2016 Elsevier B.V. All rights reserved.
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