4.7 Article

Nitrogen-rich porphyrinic metal-organic frameworks synthesized by postsynthetic metathesis: from inert material to active catalyst

Journal

SCIENCE CHINA-CHEMISTRY
Volume 59, Issue 8, Pages 975-979

Publisher

SCIENCE PRESS
DOI: 10.1007/s11426-016-0060-3

Keywords

metal-organic frameworks; porous coordination network; post-synthetic metathesis; catalysis; tetrazolate

Funding

  1. Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
  2. U.S. Department of Energy (DOE)
  3. ARPA-e [DE-AR0000249]
  4. DOE-National Energy Technology Laboratory Award [DE-FE0026472]
  5. Welch Foundation [A-1725]
  6. Welch Endowed Chair [A-0030]
  7. National Science Foundation [CHE-9807975, CHE-0079822, CHE-0215838]
  8. NSF [DBI-0116835]
  9. VP for Research Office
  10. TX Eng. Exp. Station
  11. Natural Science Foundation of China [21136001, 21276008]
  12. National Key Basic Research Program of China [2013CB733503]
  13. China Scholarship Council [201208110375]
  14. Beijing Higher Education Young EliteTeacher Project [YETP0486]

Ask authors/readers for more resources

With the aid of a postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.

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