Journal
SCIENCE CHINA-CHEMISTRY
Volume 59, Issue 2, Pages 171-174Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-015-5548-x
Keywords
visible light photocatalysis; iodide catalysis; allylation; tetrahydroisoquinolines
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Funding
- National Natural Science Foundation of China [21232003, 21202053, 21572074]
- Foundation for the Author of National Excellent Doctoral Dissertation of China [201422]
- Outstanding Youth Funding in Hubei Province [2015CFA033]
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A dual catalytic system, combing visible light photoredox catalysis and iodide catalysis, has been developed for the functionalization of inert C-H bonds. By doing so, radical allylation reactions of N-aryl-tetrahydroisoquinolines (THIQs) were realized under extremely mild conditions, affording a wide variety of allyl-substituted THIQs in up to 78% yields.
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