Journal
RUSSIAN CHEMICAL BULLETIN
Volume 65, Issue 3, Pages 840-843Publisher
SPRINGER
DOI: 10.1007/s11172-016-1387-y
Keywords
electrolysis; anodic dissolution; tin(II) oxyalcoholates; tin(II) oxyhydroxide
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Funding
- Russian Foundation for Basic Research [13-03-12237-ofi-m]
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Tin(II) alcoholates Sn(OR)(2) are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxyhydroxide Sn3O2(ODe)(2) used as an anode or its composite component in lithium cells.
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