4.1 Article

Oligomerization of higher olefins and alkylation of toluene catalyzed by 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline oxovanadium(v) complexes

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 65, Issue 11, Pages 2757-2759

Publisher

SPRINGER
DOI: 10.1007/s11172-016-1648-9

Keywords

vanadium; complexes; organoaluminum compounds; tandem catalysis; hex-1-ene; toluene; oligomerization; alkylation

Funding

  1. Russian Science Foundation [14-13-00682]
  2. Russian Science Foundation [14-13-00682] Funding Source: Russian Science Foundation

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New oxovanadium(V) complexes with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline ligands were synthesized. These compounds were found to be efficient tandem catalysts of oligomerization of hex-1-ene and alkylation of toluene, which leads to the mixture of hexyl-, dihexyl-, and trihexyltoluenes with the conversion of the starting alkene more than 99%.

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