4.1 Article

Direct functionalization of the C-H bond in (hetero)arenes: aerobic photoinduced oxidative coupling of azines with aromatic nucleophiles (SN H-reactions) in the presence of a CdS/TiO2 photocatalyst

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 65, Issue 2, Pages 445-450

Publisher

SPRINGER
DOI: 10.1007/s11172-016-1319-x

Keywords

S-N(H)-reactions; C-H functionalization; azines; aerobic photooxidation; TiO2; CdS/TiO2

Funding

  1. Ministry of Education and Science of the Russian Federation [2458]
  2. Russian Science Foundation [14-13-01177]
  3. Russian Science Foundation [14-13-01177] Funding Source: Russian Science Foundation

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A highly selective coupling of azines with aromatic nucleophiles (S-N (H)-reactions) in the presence of a heterogeneous oxidation system O-2/CdS/TiO2 upon exposure to daylight was accomplished.

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