Journal
RESEARCH ON CHEMICAL INTERMEDIATES
Volume 43, Issue 4, Pages 2445-2455Publisher
SPRINGER
DOI: 10.1007/s11164-016-2772-8
Keywords
Multicomponent reactions; Pyran annulated heterocyclic scaffolds; Aqueous ethanol; Aspartic acid
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Funding
- Postgraduate and Research Centre, Dr. Rafiq Zakaria Campus, Maulana Azad College
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Molecular diversity for the synthesis of pyran annulated heterocyclic scaffolds has been achieved from the multicomponent reaction of aldehyde, malonitrile and a third participant such as dimedone, barbituric acid and 3-methyl-1H-pyrazol-5(4H)-one. The reactions completed successfully using in situ-developed benzylidenemalononitriles via Knoevenagel reaction catalyzed by aspartic acid as a new efficient organo-catalyst in aqueous ethanol as a green medium at ambient conditions.
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