Journal
RENEWABLE ENERGY
Volume 90, Issue -, Pages 55-61Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2015.12.049
Keywords
Sewage scum; Biodiesel; Centrifugation; Direct esterification; FAMEs
Funding
- CNR through Bioraffineria di terza generazione integrata con it territorio e biocombustibili Progetto Premiale
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A very efficient separation of lipids from wet sewage scum was optimised and positively tested on samples taken from several wastewater treatment plants (WWTPs). By simply heating sewage scum at 353 K and centrifuging the heated mass at 4000 rpm per 1 min, a recoverability of 93-99% of total oils was always obtained. This procedure resulted to be effective on samples with very different starting water contents. In all cases, extracted lipids have a very similar composition in terms of free fatty acids (FFAs), calcium soaps (32-40%wt) and glycerides (mono-, di- and tri-glycerides were practically absents), as well as fatty acid profiles. Once separated, lipids were converted into biodiesel through a direct esterification process carried out by adopting three sequential batch reactors, in which methanol and catalysts were charged in counter current. In this way, the complete conversion (>99%) of starting FFAs into FAMEs was perfectly matched with using the minimum amount of reactants under very mild conditions (345 K, 2 h). The overall convenience of the process was completed by the anaerobic digestion of fibrous residues obtained from centrifugation of starting sewage scum: the final biogas resulted largely enough to sustain the heat of process. (C) 2015 Elsevier Ltd. All rights reserved.
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