Production of biodiesel from castor oil using iron (II) doped zinc oxide nanocatalyst

The depletion of fossil fuels has caused the price of petroleum to rise remarkably and created need for alternative energy such as biodiesel. In the present study, the biodiesel was produced from castor oil using ferromagnetic zinc oxide nanocomposite as heterogeneous catalyst for transesterification reaction. Single phase of nanocatalyst were confirmed by X-Ray Diffraction analysis. The spherical shape of the aggregated nanocatalyst was observed in Scanning Electron Microscopy. Magnetic properties were analysed using vibrating sample magnetometer. Atomic Force Microscopic analysis revealed the larger surface area and roughness of nanocatalyst. The biodiesel yield of 91% (w/w) was obtained in 50 min at 55 degrees C with 14 wt % catalyst loading and 12:1 methanol/oil ratio and was confirmed by Gas chromatograph with Mass Spectrometer. The result showed that the iron (II) doped ZnO nanocatalyst is a promising catalyst for the production of biodiesel via heterogeneous catalytic transesterification under milder reaction conditions. (C) 2016 Elsevier Ltd. All rights reserved.