4.4 Article

Total Synthesis of Longistylin A, Longistylin C and Cajanotone

Journal

CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 35, Issue 5, Pages 1146-1151

Publisher

SCIENCE PRESS
DOI: 10.6023/cjoc201410024

Keywords

longistylin A; longistylin C; cajanotone; total synthesis

Funding

  1. Program for New Century Excellent Talents in University [NCET-12-0656]
  2. Innovation Ability Promoting Program in University of Guizhou Province [2013-04]
  3. Natural Science Fundation for Youth in Universities of Guizhou Province [2014-300]

Ask authors/readers for more resources

Natural products longistylin A, longistylin C and cajanotone belong to stilbenes family and exhibit varieties of bioactivities. Using Horner-Wadsworth-Emmons (HWE) and 1,3-sigma rearrangement reactions as key steps, longistylin A and longistylin C have been successfully synthesized in six steps from 3,5-dimethoxy benzoic acid. Besides, using Barbier and 1,3-sigma rearrangement reactions as key steps, cajanotone has been first prepared in eight steps from 3,5-dihydroxy benzoic acid.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available