Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 33, Issue 7, Pages 705-710Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201500167
Keywords
palladium; cross-coupling; palladacycle; N-ligands; green chemistry
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Funding
- National Natural Science Foundation of China [20702051]
- Natural Science Foundation of Zhejiang Province [LY13B020017]
- Key Innovation Team of Science and Technology in Zhejiang Province [2010R50018]
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A novel water-soluble, phosphine-free PEG click triazole palladacycle has been successfully synthesized. As a precatalyst, the palladacycle exhibited superior catalytic activity towards Suzuki-Miyaura and copper-free Sonogashira cross-coupling in neat water with the turnover numbers (TONs) of up to 9.8x10(5). In addition, the catalyst could be reused at least 3 times without significant loss of reactivity.
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