Journal
CHINESE CHEMICAL LETTERS
Volume 26, Issue 6, Pages 646-648Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2015.03.019
Keywords
Cycloaddition; Allylic carbonate; Ylides; Trifluoromethyl ketones
Categories
Funding
- National Natural Science Foundation of China [21302034]
- Fundamental Research Funds for the Central Universities [2013HGQC0028]
Ask authors/readers for more resources
A phosphine-promoted [3 + 2] cycloaddition from readily accessible MBH (Morita-Baylis-Hillman) carbonate and aryl trifluoromethyl ketone is described. The use of methyl vinyl ketone-derived allylic carbonate rather than common acrylate-derived counterpart renders the reaction pathway exclusive for 5-endo process, which enables the expeditious preparation of a range of trifluoromethylated 2, 3-dihydrofuran in a chemospecific manner. (C) 2015 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
