4.7 Article

Diselenide covalent chemistry at the interface: stabilizing an asymmetric diselenide-containing polymer via micelle formation

Journal

POLYMER CHEMISTRY
Volume 7, Issue 44, Pages 6708-6713

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6py01610c

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Funding

  1. National Science Foundation for Distinguished Young Scholars [21425416]
  2. National Basic Research Program of China [2013CB834502]
  3. Foundation for Innovative Research Groups of the National Natural Science Foundation of China [21421064]
  4. National Natural Science Foundation of China [91427301]

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We demonstrated the proof-of-concept that diselenide dynamic chemistry can be performed at an oil/water interface. An asymmetric diselenide-containing polymer, which would decompose under visible light once separated from the metathesis mixture, was successfully stabilized via a micelle induced stabilization method.

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