Journal
POLYMER CHEMISTRY
Volume 7, Issue 18, Pages 3067-3070Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6py00221h
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Funding
- Max Planck Society
- University of Potsdam
- National Science Foundation Postdoctoral Research Fellowship in Biology [DBI-1308104]
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Polysarcosine (M-n = 3650-20 000 g mol(-1), D similar to 1.1) was synthesized from the air and moisture stable N-phenoxycarbonyl-N-methylglycine. Polymerization was achieved by in situ transformation of the urethane precursor into the corresponding N-methylglycine-N-carboxyanhydride, when in the presence of a non-nucleophilic tertiary amine base and a primary amine initiator.
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