Journal
POLYMER CHEMISTRY
Volume 7, Issue 36, Pages 5641-5645Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6py01046f
Keywords
-
Categories
Funding
- Spanish Xunta de Galicia [08TMT002209PR]
- MINECO (FEDER) [MAT2013-42425-R]
- Chile Government
Ask authors/readers for more resources
We report the first examples of a new class of rigid dendrimers made of three-dimensional tetraphenylmethane units connected by ethynylene linkers. Designed to obtain a persistent globular shape, minimal backfolding of terminal groups and well-defined cavities at low generations, the dendrimers were synthesized until the second generation by a convergent strategy based on Sonogashira couplings. Their structure and size were confirmed by NMR, MALDI-TOF-MS and SEC among other techniques. The dendrimers showed intrinsic fluorescence with quantum yields of similar to 0.6.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available