Journal
POLYMER CHEMISTRY
Volume 7, Issue 47, Pages 7199-7203Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6py01844k
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Funding
- German Academic Exchange Service (DAAD)
- Max Planck Society
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A Cu(II) MOF can serve as an efficient catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), e.g. for the synthesis of poly(benzyl methacrylate) (PBzMA) and polystyrene (PS). Furthermore, poly(isoprene) (PI) and poly(4-vinylpyridine) (P4VP) can be formed in a controlled fashion as well, which used to be challenging to achieve by traditional strategies. Taking advantage of the heterogeneous nature of the catalyst, recycling via centrifugation and repeated utilization for at least six cycles are demonstrated.
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