Journal
POLYMER
Volume 82, Issue -, Pages 93-99Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2015.11.043
Keywords
Functional adhesives; Epoxy; Electrical conductivity
Categories
Funding
- Japanese Ministry of Education, Culture, Sports, Science, and Technology [24360280]
- Grants-in-Aid for Scientific Research [15H04135] Funding Source: KAKEN
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Diglycidyl ethers of bisphenol-A (DGEBA)/4,4'-diaminodiphenylmethane (DDM)/polyethersulphone (PES) blends were prepared as matrix resins for electrically conductive adhesives containing silver (Ag) fillers. The epoxy/PES blends formed co-continuous phase structures from initial homogeneous solutions via reaction-induced phase separation during the curing process. The Ag fillers were selectively localized in the epoxy-rich phases that had high affinity toward the surface of the Ag fillers. The co-continuous phase structures of the epoxy/PES blends acted as templates for the three-dimensional continuous structures of the Ag fillers. The self-assembled structures of the Ag fillers were connected in a continuous phase that possessed high electrical conductivity using a relatively small amount of Ag filler. In addition, the epoxy/PES/Ag adhesives had excellent shear adhesive strength. The fracture toughness of the epoxy/PES blends was the source of the high adhesive strength. (C) 2015 Elsevier Ltd. All rights reserved.
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