Journal
POLYHEDRON
Volume 108, Issue -, Pages 8-14Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2015.07.070
Keywords
Carbene; Synthesis; Rhodium; Coordination complex; N-Heterocyclic olefins
Categories
Funding
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- American Chemical Society (Petroleum Research Fund)
- Alexander von Humboldt Foundation
Ask authors/readers for more resources
An improved synthesis of N-heterocyclic olefins (NHOs) containing terminal CH2 donor groups was developed. A preliminary investigation of the bonding mode and donor strengths of various structurally distinct NHOs was conducted by analysis of the IR and NMR spectra of their corresponding rhodium carbonyl complexes NHO center dot RhCl(CO)(2), along with examination of pertinent metrical parameters via X-ray crystallography and Density Functional Theory (DFT) computations. (C) 2015 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available