Journal
CHEMSUSCHEM
Volume 8, Issue 11, Pages 1841-1844Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201403466
Keywords
addition reactions; bismuth oxide; photocatalysis; radical reactions; visible light
Funding
- Institute of Chemical Research of Catalonia (ICIQ) Foundation
- MINECO [CTQ2012-38594-C02-01, SEV-2013-0319]
- EU-ITN network Mag(net)icFun [PITN-GA-2012-290248]
- DEC Generalitat de Catalunya [2014SGR827]
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Bismuth oxide, an inexpensive and non-toxic semiconductor, has been successfully used as a visible light photocatalyst for the atom transfer radical addition (ATRA) reaction of organobromides to diversely functionalized terminal olefins. The reaction takes place under very mild conditions, in the absence of any additive, and with low catalyst loading (1mol%). The corresponding ATRA products are obtained with moderate to excellent yields (up to 95%).
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