4.5 Article

Dispersion of Polymers in Metallic Gallium

Journal

CHEMPHYSCHEM
Volume 17, Issue 1, Pages 162-169

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201500899

Keywords

gallium; polycaprolactone; polymers; solubilization; sonication

Funding

  1. Israel Science Foundation [703/12]
  2. FTA Program of the Ministry of Commerce and Industry (Israel)

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This work examines the concept of dispersing polymers in metals. Herein, this was mainly studied with molten gallium, in which 5-18wt% of various short-chain polymers were incorporated and mixed. The nature of the solidified products was examined by using X-ray diffraction, electron microscopy, UV/Vis, differential scanning calorimetry, and thermal gravimetric analyses. It was found that some polymers can be dispersed as small domains within molten metals to form a heterogeneous solid. The ability to dope Ga with large polymers opens a new avenue to electronic materials.

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