Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 18, Issue 10, Pages 7341-7348Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cp00002a
Keywords
-
Funding
- National Key Basic Research Program of China [2014CB931804]
- National Natural Science Foundation of China [51173017, 51373024, 51473020, 61370048]
- Beijing Higher Education Young Elite Teacher Project [YETP0356]
- Fundamental Research Funds for the Central Universities [FRF-TP-14-001A2]
Ask authors/readers for more resources
A novel kind of monodonor-bisacceptor (D-A-A) C60 charge-transfer complex was synthesized by the high-yielding [2+2] click chemistry reaction and the Prato reaction. Both electrochemical and UV-vis spectra studies were carried out and they proved that the side groups of the fullerene derivatives played an important role in the energy gaps, and also affected the third-order non-linear optical response. The experimental investigation on the third-order non-linear optical phenomena of the fullerene derivatives was measured using the Z-scan technique at different wavelengths (532 nm and 1064 nm). All the compounds exhibited very special non-linear optical properties when pumped by 21 ps pulses at 532 nm which suggested that there were two different types of reversible photo-isomerization. The optical-limiting performance has also been studied which proved indirectly the mechanism models of the reversible photo-isomerization.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available