Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 18, Issue 38, Pages 26412-26422Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cp05437d
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Funding
- EPSRC [EP/N006895/1]
- EPSRC [EP/N006895/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/N006895/1] Funding Source: researchfish
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This paper presents a detailed analysis of the pseudocontact shift (PCS) field induced by a mobile spin label that is viewed as a probability density distribution with an associated effective magnetic susceptibility anisotropy. It is demonstrated that non-spherically symmetric density can lead to significant deviations from the commonly used point dipole approximation for the PCS. Analytical and numerical solutions are presented for the general partial differential equation that describes the non-point case. It is also demonstrated that it is possible, with some reasonable approximations, to reconstruct paramagnetic centre probability distributions from the experimental PCS data.
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