4.6 Article

Enhanced photoelectric properties by the coordinating role of doping and modification

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 18, Issue 6, Pages 4850-4859

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp07159c

Keywords

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Funding

  1. National Natural Science Foundation of China [21341007]
  2. Key Laboratory for Ultrafine Materials of The Ministry of Education Foundation
  3. Fundamental Research Funds for the Central Universities [222201313005]
  4. State Key Laboratory of Pollution Control and Resource Reuse Foundation [13019]

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Dual technique design in this research has successfully enriched the complementation between doping and surface modification. Here, Co2+ doped Ag-ZnO nanocomposites (CAZ NCs) are mass produced by the combustion method. The HRTEM image shows that the doped Co2+ and the surface modified Ag nanoparticles on the ZnO NCs are influential on the preferential orientation. Based on the conductivity formula sigma = nq mu and the actual verification, the improved photoelectric properties of CAZ NCs under visible light irradiation are attributed to the enhanced light absorption and the weakened recombination of photogenerated electron-hole pairs. It would be instructive for the sound design concept of subsequent material development.

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