Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 191, Issue 11-12, Pages 1625-1627Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2016.1217222
Keywords
Anchimeric assistance; conjugate addition; rate-determining step; solvent isotope effect; tertiary phosphines
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The Michael-type addition of tertiary phosphines to electron-deficient alkenes is a convenient way to generate reactive phosphonium zwitterionic intermediates, which participate readily in many synthetically useful transformations. Although the synthetic usefulness of the phospha-Michael addition has been largely demonstrated, knowledge on the kinetics and mechanism of this reaction is sparse. This paper briefly summarizes the contribution of our research group to find out the mechanism of this reaction. [GRAPHICS] .
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