4.1 Article Proceedings Paper

New 18-membered tetrakisphosphine macrocycle and its derivatives

Journal

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 191, Issue 11-12, Pages 1591-1592

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2016.1216424

Keywords

Aminomethylphosphine; macrocycles; gold complex

Funding

  1. Russian Science Foundation [15-13-30031] Funding Source: Russian Science Foundation

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The novel 18-membered aminomethylphosphine was obtained by the reaction of 1,4-bis(2-pyridylphosphine)butane with paraformaldehyde and 4-methylbenzylamine as RSSR-isomer. Its tetraoxide and tetragold complex were obtained by the oxidation and interaction with gold chloride respectively. According to the X-Ray data the structure of oxidized product is similar to the structure of linear tetragold complex. [GRAPHICS] .

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