Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 191, Issue 4, Pages 668-670Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2015.1128933
Keywords
Phosphine; dehydrocoupling catalysis; zirconium; diphosphine
Categories
Funding
- U.S. National Science Foundation [CHE-0747612, CHE-1265608]
- Alexander von Humboldt Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1265608] Funding Source: National Science Foundation
Ask authors/readers for more resources
Zirconium compounds are known to dehydrocouple phosphines catalytically. An exploration of the factors that may promote selective heterodehydrocoupling was performed, revealing that steric factors are important but do not provide substantial selectivity. It was observed that (5)-(Me3SiNCH2CH2)(2)N(CH2CH2NSiMe2CH2)Zr (1) may be sufficiently Lewis acidic to perform Lewis acid or frustrated Lewis pair catalysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
