4.6 Article

Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 10, Issue 10, Pages 2139-2142

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201403408

Keywords

cyclopropenylidene; gold; hydrazine; hydroamination; mesoionic carbene

Funding

  1. DOE [DE-FG02-13ER16370]

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A novel synthetic route gives access to mesoionic carbene and cyclopropenylidene supported gold chloride complexes. The corresponding cationic MIC-gold complex obtained by chloride abstraction allows for the first transition metal-catalyzed functionalization of both nitrogens of parent hydrazine.

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