Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 10, Issue 4, Pages 869-872Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201403312
Keywords
conjugate addition; europium; indoles; natural products; -unsaturated enones
Categories
Funding
- Ministry of Science Technology [2013CB836900]
- National Natural Science Foundation of China [21290180, 21172235, 21222202]
- Pujiang Program [12J1410800]
- Chinese Academy of Sciences
- China Postdoctoral Science Foundation [2014M551480]
Ask authors/readers for more resources
The chemical synthesis of indole terpenoids of structural and biological interests has attracted remarkable attention. Here we report an Eu(fod)(3)-catalyzed indole conjugate addition reaction, which tolerates various acid-sensitive functional groups. A collection of indole terpenoid mimics have been prepared from natural product-derived ,-unsaturated enones on the basis of this reaction. The further conversion of the indole adducts into more complex natural product-like molecules has also been demonstrated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available