4.6 Article

Defect-Controlled Preparation of UiO-66 Metal-Organic Framework Thin Films with Molecular Sieving Capability

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 11, Issue 2, Pages 207-210

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201501079

Keywords

metal-organic frameworks; molecular sieving; porous materials; thin films

Funding

  1. National Natural Science Foundation of China [21371127]
  2. Soochow University
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  4. Young Thousand Talented Program

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Metal-organic framework (MOF) UiO-66 thin films are solvothermally grown on conducting substrates. The as-synthesized MOF thin films are subsequently dried by a supercritical process or treated with polydimethylsiloxane (PDMS). The obtained UiO-66 thin films show excellent molecular sieving capability as confirmed by the electrochemical studies for redox-active species with different sizes.

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