Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 10, Issue 12, Pages 2593-2597Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201500743
Keywords
bispyridium salt; boronlectin; lactose; oligosaccharides; sensors
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Funding
- Natural Science Foundation of China [21272027]
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N,N-Di-2-picolylamine (DPA)-derived diboronic acid receptors (NHBAs) with a flexible linker were designed and synthesized in this study, and two-component sensing ensembles based on cationic NHBAs and an anionic fluorescent indicator 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt (HPTS) were successfully developed for both monosaccharides and disaccharides sensing. The dibranched ortho-substituted receptor NHoBA exhibited unexpected selectivity towards lactose among five disaccharides used. The discrimination of five disaccharides and six monosaccharides was finally achieved by the integrated sensor array through linear discriminant analysis (LDA).
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